GATE Chemistry CY Syllabus 2019 Download GATE Syllabus & Full Paper Pattern

GATE Entrance Examination 2019 Syllabus

Recently, the Indian Institue of Technology Guwahati has released a notification for GATE 2019. Graduate Aptitude Test for Engineering is going to be conducted by IITG this year. The GATE 2019 Notification has been released. Candidates who have applied for Chemistry and want to appear in this exam may download & check the GATE Chemistry CY Syllabus. Check this page till the end for Section wise Complete syllabus & exam pattern.

GATE Chemistry CY Syllabus

GATE Chemistry CY Syllabus

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GATE Chemistry CY Syllabus

Section 1: Physical Chemistry

Structure

Postulates of quantum mechanics

Time-dependent and time-independent Schrödinger equations

Born interpretation

Particle in a box

Harmonic oscillator

Rigid rotor

Hydrogen atom: atomic orbitals

Multi-electron atoms: orbital approximation

Variation and first-order perturbation techniques

Chemical bonding: Valence bond theory and LCAO-MO theory

Hybrid orbitals

Applications of LCAO-MOT to H2+, H2, and other homonuclear diatomic molecules, heteronuclear diatomic molecules like HF, CO, NO, and to simple delocalized π– electron systems

Hückel approximation and its application to annular π – electron systems

Symmetry elements and operations

Point groups and character tables

Origin of selection rules for rotational, vibrational, electronic and Raman spectroscopy of diatomic and polyatomic molecules

Einstein coefficients

Relationship of transition moment integral with molar extinction coefficient and oscillator strength

Basic principles of nuclear magnetic resonance: nuclear g factor, chemical shift, nuclear coupling

Equilibrium

Laws of thermodynamics

Standard states

Thermochemistry

Thermodynamic functions and their relationships: Gibbs-Helmholtz and Maxwell relations, van’t Hoff equation

Criteria of spontaneity and equilibrium

Absolute entropy

Partial molar quantities

Thermodynamics of mixing

Chemical potential

Fugacity, activity and activity coefficients

Chemical equilibria

Dependence of equilibrium constant on temperature and pressure

Non-ideal solutions

Ionic mobility and conductivity

Debye-Hückel limiting law

Debye-Hückel-Onsager equation

Standard electrode potentials and electrochemical cells

Potentiometric and conductometric titrations

Phase rule

Clausius Clapeyron equation

Phase diagram of one component systems: CO2, H2O, S

Two-component systems: liquid-vapor, liquid-liquid and solid-liquid systems

Fractional distillation

Azeotropes and eutectics

Statistical thermodynamics: microcanonical and canonical ensembles, Boltzmann distribution, partition functions and thermodynamic properties

Kinetics

Transition state theory: Eyring equation, thermodynamic aspects

Potential energy surfaces and classical trajectories

Elementary, parallel, opposing and consecutive reactions

Steady-state approximation

Mechanisms of complex reactions

Unimolecular reactions

Kinetics of polymerization and enzyme catalysis

Fast reaction kinetics: relaxation and flow methods

Kinetics of photochemical and photophysical processes

Surfaces and Interfaces

Physisorption and chemisorption

Langmuir, Freundlich and BET isotherms

Surface catalysis: Langmuir-Hinshelwood mechanism

Surface tension, viscosity

Self-assembly

Physical chemistry of colloids, micelles, and macromolecules

GATE Chemistry CY Syllabus

Section 2: Inorganic Chemistry

Main Group Elements

Hydrides, halides, oxides, oxoacids, nitrides, sulfides – shapes and reactivity

Structure and bonding of boranes, carboranes, silicones, silicates, boron nitride, borazines and phosphazenes

Allotropes of carbon

Chemistry of noble gases, pseudohalogens, and interhalogen compounds

Acid-base concepts

Transition Elements

Coordination chemistry-structure and isomerism, theories of bonding (VBT, CFT, and MOT)

Energy level diagrams in various crystal fields, CFSE, applications of CFT, Jahn-Teller distortion

Electronic spectra of transition metal complexes: spectroscopic term symbols, selection rules, Orgel diagrams, charge-transfer spectra

Magnetic properties of transition metal complexes

Reaction mechanisms: kinetic and thermodynamic stability, substitution and redox reactions

Lanthanides and Actinides: Recovery. Periodic properties, spectra, and magnetic properties.

Organometallics

18-Electron rule; metal-alkyl, metal-carbonyl, metal-olefin and metal carbene complexes and metallocenes

Fluxionality in organometallic complexes

Types of organometallic reactions

Homogeneous catalysis – Hydrogenation, hydroformylation, acetic acid synthesis, metathesis and olefin oxidation

Heterogeneous catalysis – Fischer Tropsch reaction, Ziegler-Natta polymerization

Radioactivity: Decay processes, the half-life of radioactive elements, fission and fusion processes.
Bioinorganic Chemistry: Ion (Na+ and K+) transport, oxygen binding, transport and utilization, electron transfer reactions, nitrogen fixation, metalloenzymes containing magnesium, molybdenum, iron, cobalt, copper, and zinc.
Solids: Crystal systems and lattices, Miller planes, crystal packing, crystal defects, Bragg’s law, ionic crystals, structures of AX, AX2, ABX3 type compounds, spinels, band theory, metals, and semiconductors

Instrumental Methods of Analysis

UV-visible spectrophotometry, NMR and ESR spectroscopy, mass spectrometry

Chromatography including GC and HPLC

Electroanalytical methods- polarography, cyclic voltammetry, ion-selective electrodes

Thermoanalytical methods

GATE Chemistry CY Syllabus

Section 3: Organic Chemistry

Stereochemistry

Chirality of organic molecules with or without chiral centers and determination of their absolute configurations

Relative stereochemistry in compounds having more than one stereogenic center

Homotopic, enantiotopic and diastereotopic atoms, groups, and faces

Stereoselective and stereospecific synthesis

Conformational analysis of acyclic and cyclic compounds

Geometrical isomerism

Configurational and conformational effects, and neighboring group participation on reactivity and selectivity/specificity

Reaction Mechanisms

Basic mechanistic concepts-Kinetic versus thermodynamic control, Hammond’s postulate and Curtin-Hammett principle

Methods of determining reaction mechanisms through identification of products, intermediates and isotopic labeling

Nucleophilic and electrophilic substitution reactions (both aromatic and aliphatic)

Addition reactions to carbon-carbon and carbon-heteroatom (N.O.) multiple bonds

Elimination reactions

Reactive intermediates – carbocations, carbanions, carbenes, nitrenes, arynes and free radicals

Molecular rearrangements involving electron deficient atoms

Organic Synthesis

Synthesis, reactions, mechanisms and selectivity involving the following classes of compounds – alkenes, alkynes, arenes, alcohols, phenols, aldehydes, ketones, carboxylic acids, esters, nitriles, halides, nitro compounds, amines and amides

Uses of Mg, Li, Cu, B, Zn and Si-based reagents in organic synthesis

Carbon-carbon bond formation through coupling reactions – Heck, Suzuki, Stille and Sonogoshira

Concepts of multistep synthesis – retrosynthetic analysis, strategic disconnections, synthons and synthetic equivalents

Umpolung reactivity – formyl and acyl anion equivalents

Selectivity in organic synthesis-Chemo-, regio- and stereoselectivity

Protection and deprotection of functional groups

Concepts of asymmetric synthesis – resolution (including enzymatic), desymmetrization and use of chiral auxiliaries

Carbon-carbon bond forming reactions through enolates (including boron enolates), enamines and silyl enol ethers

Michael addition reaction

Stereoselective addition to C=O groups (Cram and Felkin-Anh models)

Pericyclic Reactions and Photochemistry

Electrocyclic, cycloaddition and sigmatropic reactions

Orbital correlations – FMO and PMO treatments

Photochemistry of alkenes, arenas and carbonyl compounds

Photooxidation and photoreduction

Di-π-methane rearrangement, Barton reaction

Heterocyclic Compounds: Structure, preparation, properties, and reactions of furan, pyrrole, thiophene, pyridine, indole, quinoline and isoquinoline.
Biomolecules: Structure, properties and reactions of mono- and di-saccharides, physicochemical properties of amino acids, chemical synthesis of peptides, structural features of proteins, nucleic acids, steroids, terpenoids, carotenoids, and alkaloids.
Spectroscopy: Applications of UV-visible, IR, NMR and Mass spectrometry in the structural determination of organic molecules.

Some Important Links for GATE 2019 & 

GATE Chemistry CY Syllabus

GATE Previous Exam (Sample Paper)

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GATE 2019 Code Wise Syllabus

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Official Website

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GATE 2019 (CY) Official Syllabus

Download CY Syllabus for Gate 2019

 

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